Synthesis of 1,3-Diphenyl-4,5-bis(hydroxyimino)imidazolidine and its complexes with Nickel(II), Cobalt(II), Copper(II), Palladium(II), and Uranyl(VI)

Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/20813

Title:	Synthesis of 1,3-Diphenyl-4,5-bis(hydroxyimino)imidazolidine and its complexes with Nickel(II), Cobalt(II), Copper(II), Palladium(II), and Uranyl(VI)
Authors:	Uludağ Üniversitesi/Mühendislik Fakültesi. 0000-0002-9249-2385 Ahsen, Vefa Bekaroğlu, Özen N-9731-2013
Keywords:	Chemistry
Issue Date:	28-Aug-1984
Publisher:	Marcel Dekker
Citation:	Ahsen, V. ve Bekaroğlu, Ö. (1984). "Synthesis of 1,3-Diphenyl-4,5-bis(hydroxyimino)imidazolidine and its complexes with Nickel(II), Cobalt(II), Copper(II), Palladium(II), and Uranyl(VI)". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 15(1), 61-73.
Abstract:	1, 3-Dipheny1-4, 5-bis(hydroxyimino)imidazolidine (LH2) has been prepared from anti-dichloroglyoxime, N,N′-diphenylmethylenediamine, and sodium bicarbonate in ethanol. Complexes of Cu(II), Ni(II), Co(II), Pd(II), and UO2(VI) and LH2 give a metal-ligand ratio of 1:2. A tetrahedral complex is obtained for the Ni(II) complex by coordination through N and O atoms. The (LH2)Co. H2O complex is squarepyramidal while the Cu(II), Pd(II) and UO2(VI) complexes are square-planar. The structures of the ligand and complexes are proposed based on elemental analysis, mass spectral, H-n.m.r., i.r., u. v. -visible, and magnetic data.
URI:	https://doi.org/10.1080/00945718508059367 https://www.tandfonline.com/doi/abs/10.1080/00945718508059367 http://hdl.handle.net/11452/20813
ISSN:	2470-1556 2470-1564
Appears in Collections:	Web of Science

Files in This Item:

There are no files associated with this item.

DSpace JSPUI