Direct conversion of aldehydes into nitriles via O-phenylcarbamoylated aldoximes

Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/21095

Title:	Direct conversion of aldehydes into nitriles via O-phenylcarbamoylated aldoximes
Authors:	Uludağ Üniversitesi/Fen Edebiyat Fakültesi/Kimya Bölümü. Coşkun, Necdet Arıkan, Nevin AAH-6337-2021
Keywords:	Chemistry
Issue Date:	1-Oct-1999
Publisher:	Pergamon-Elsevier Science
Citation:	Coşkun, N. ve Arıkan, N. (1999). "Direct conversion of aldehydes into nitriles via O-phenylcarbamoylated aldoximes". Tetrahedron, 55(40), 11943-11948.
Abstract:	O-Arylcarbamoylated hydroxylamine tosylate reacts with aldehydes at room temperature to give the corresponding O-carbamoylated oximes. The reaction of carbamoylated hydroxylamine with aromatic aldehydes in THF or in toluene at reflux affords the corresponding nitriles and anilinium tosylate in high yield. Attempts to cyclize compounds 2 in the presence of AcCl lead again to the formation of nitriles.
URI:	https://doi.org/10.1016/S0040-4020(99)00692-4 https://www.sciencedirect.com/science/article/pii/S0040402099006924 http://hdl.handle.net/11452/21095
ISSN:	0040-4020
Appears in Collections:	Web of Science

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