Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/22459
Title: Synthesis and evaluation of new long alkyl side chain acetamide, isoxazolidine and isoxazoline derivatives as corrosion inhibitors
Authors: Uludağ Üniversitesi/Fen Bilimleri Enstitüsü/Kimya Anabilim Dalı.
0000-0002-2328-9754
Yıldırım, Ayhan
Çetin, Mehmet
W-8924-2019
23101773900
7101936230
Keywords: Acetamide
Isoxazolidine
Corrosion inhibitors
Acidic medium
Oil medium
Aromatic nitrile oxides
Mild-steel corrosion
Acidic medium
secondary-amines
Oxidation
Hydroxylamines
Nitrones
Heterocycles
N -80
Corrosion inhibitors
Cycloaddition
Nitrogen compounds
Nuclear magnetic resonance spectroscopy
Synthesis (chemical)
Corrosion inhibitors
Cycloaddition
Nuclear magnetic resonance spectroscopy
Acetamide
Isoxazolidine
Isoxazoline
Nitrogen compounds
Issue Date: Jan-2008
Publisher: Pergamon-Elsevıer Science
Citation: Ayhan, Y. ve Mehmet, Ç. (2008). ''Synthesis and evaluation of new long alkyl side chain acetamide, isoxazolidine and isoxazoline derivatives as corrosion inhibitors''. Corrosion Science, 50(1), 155-165.
Abstract: 2-(Alkylsulfanyl)-N-(pyridin-2-yl) acetamide derivatives were synthesized via amidation reaction of acyl chlorides bearing S atom in the long chain with 2-aminopyridine. Derivatives of isoxazolidine and isoxazoline were synthesized through 1,3-dipolar cycloaddition reactions with three different long chain alkenes containing O or S as hetero atoms and C,N-diphenyl nitrone or benzonitrile-N-oxide, respectively. Synthesized compounds were characterized with their FT-IR, H-1 NMR spectra and then their physical properties and corrosion prevention efficiencies were investigated. All compounds were tested with steel coupons in acidic medium by gravimetric method, and also some of them were tested with steel stripe in paraffin based mineral oil medium via standard method. Acidic test was done with a medium concentration of 2 M HCI for 20 h at room temperature. Mineral oil was used and the test in this medium was done at 60 degrees C constant temperature but varying time from 42 to 63 It. The best inhibition was generally obtained at 50 ppm inhibitor concentration in the acidic medium. All tested inhibitors except two of them in oil medium also showed promising inhibition efficiencies.
URI: https://doi.org/10.1016/j.corsci.2007.06.015
http://hdl.handle.net/11452/22459
ISSN: 0010-938X
https://www.sciencedirect.com/science/article/pii/S0010938X07001862
Appears in Collections:Scopus
Web of Science

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