Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/24378
Title: A novel reaction of α-carbonyl oxime and amido alcohol: Synthesis, characterization, crystal structure, and thermal studies of an amido alcohol, a new oximino alcohol ligand, and its metal complexes
Authors: Büyükgüngör, Orhan
Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.
0000-0002-0026-7755
Kaya, Yunus
İrez, Gazi
Mutlu, Hasene
AAH-2888-2021
35181446100
6602755323
57212275330
Keywords: Chemistry
Science & technology - other topics
Oximino alcohol
Reduction
Amido alcohol
Schiff-base ligands
Cu(II)
Copper(II)
Co(II)
Ni(II)
Nickel(II)
Cobalt(II)
Zinc(II)
Dioxime
Issue Date: 2011
Publisher: Taylor & Francis
Citation: Kaya, Y. vd. (2011). ''A novel reaction of α-carbonyl oxime and amido alcohol: Synthesis, characterization, crystal structure, and thermal studies of an amido alcohol, a new oximino alcohol ligand, and its metal complexes''. Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 41(7), 754-762.
Abstract: In this study, a novel reaction was observed between isonitrosoacetophenone and 1-phenylethanol amine. Acetophenone was used as a starting material to synthesize isonitrosoacetophenone by reaction of acetophenone with n-butyl nitrite in the presence of sodium ethoxide and to synthesize 1-phenylethanol amine by reduction of isonitrosoacetophenone with LiAlH4 in diethyl ether. When the isonitrosoacetophenone reacted with 1-phenylethanol amine, (3E)-3-aza-5-(hydroxyimino)1,4-diphenylpent-3-en-1-ol monohydrate, a new oximino alcohol ligand and amido alcohol were obtained as associated product interestingly. Four complexes were prepared by treatment of oximino alcohol with metal salts such as Cu-II, Ni-II, Zn-II, and Co-II. Amido alcohol was characterized by single-crystal x-ray diffraction, and all complexes were characterized by using spectroscopic techniques and thermogravimetric analysis (TGA).
URI: https://doi.org/10.1080/15533174.2011.591300
https://www.tandfonline.com/doi/full/10.1080/15533174.2011.591300
http://hdl.handle.net/11452/24378
ISSN: 1553-3174
1553-3182
Appears in Collections:Scopus
Web of Science

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