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http://hdl.handle.net/11452/29064
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DC Field | Value | Language |
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dc.contributor.author | Mirtamizdoust, Babak | - |
dc.contributor.author | Bienko, Dariusz C. | - |
dc.contributor.author | Hanifehpour, Younes | - |
dc.contributor.author | Tiekink, Edward R. T. | - |
dc.contributor.author | Talemi, Pejman | - |
dc.contributor.author | Joo, Sang Woo | - |
dc.date.accessioned | 2022-10-12T10:45:01Z | - |
dc.date.available | 2022-10-12T10:45:01Z | - |
dc.date.issued | 2016-07 | - |
dc.identifier.citation | Mirtamizdoust, B. vd. (2016). "Preparation of a novel nano-scale lead (II) zigzag metal-organic coordination polymer with ultrasonic assistance: Synthesis, crystal structure, thermal properties and NBO analysis of [Pb(μ-2-pinh)(N3)OH2]n". Journal of Inorganic and Organometallic Polymers and Materials, 26(4), 819-828. | en_US |
dc.identifier.issn | 1574-1443 | - |
dc.identifier.issn | 1574-1451 | - |
dc.identifier.uri | https://doi.org/10.1007/s10904-016-0385-8 | - |
dc.identifier.uri | https://link.springer.com/article/10.1007/s10904-016-0385-8 | - |
dc.identifier.uri | http://hdl.handle.net/11452/29064 | - |
dc.description.abstract | A novel nano-cauliflower-shaped lead(II) metal-organic coordination polymer, [Pb(mu-2-pinh)N-3 H2O](n) (1), was synthesized using an ultrasonic method. The nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction, IR spectroscopy, elemental analysis, and thermal analysis. The compound was structurally characterized by single-crystal X-ray diffraction. The coordination compound takes the form of a zig-zag one-dimensional polymer in solid state. The coordination number of the lead(II) ions is six (PbN4O2) with three nitrogen atoms and one oxygen atom from two linker organic ligands, as well as one oxygen from coordinated water and one nitrogen atom from terminal coordinated azide anion. It has a stereo-chemically active lone electron pair, and the coordination sphere is hemidirected. The zig-zag 1D chains interact with neighbouring chains through weak interactions, creating a 3D supramolecular metal-organic framework. Lead oxide nanoparticles were obtained by thermolysis of the new nano coordination compound at 180 A degrees C with oleic acid as a surfactant. The morphology and size were further studied using SEM. Natural bond orbital analyses demonstrate the electronic properties of the lead centre and other atoms. | en_US |
dc.description.sponsorship | University of Qom | en_US |
dc.description.sponsorship | National Research Foundation of Korea - NRF-2015-002423 | en_US |
dc.description.sponsorship | Polish Ministry of Science and Higher Education for the Faculty of Chemistry of Wroclaw University of Technology | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.rights | Atıf Gayri Ticari Türetilemez 4.0 Uluslararası | tr_TR |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Polymer science | en_US |
dc.subject | Nano zig-zag polymer | en_US |
dc.subject | Nano metal-organic coordination compound | en_US |
dc.subject | NBO analysis | en_US |
dc.subject | Lead(II) nanoparticle | en_US |
dc.subject | Natural steric analysis | en_US |
dc.subject | Dft calculations | en_US |
dc.subject | Sonochemical synthesis | en_US |
dc.subject | Pb(II) coordination | en_US |
dc.subject | Inclusion complex | en_US |
dc.subject | Lone-pair | en_US |
dc.subject | 3,4,7,8-tetramethyl-1,10-phenanthroline | en_US |
dc.subject | Thiocyanate | en_US |
dc.subject | Precursor | en_US |
dc.subject | Atoms | en_US |
dc.subject | Chains | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Electronic properties | en_US |
dc.subject | Lead | en_US |
dc.subject | Metal analysis | en_US |
dc.subject | Metal nanoparticles | en_US |
dc.subject | Metals | en_US |
dc.subject | Nanoparticles | en_US |
dc.subject | Nanostructures | en_US |
dc.subject | Nanotechnology | en_US |
dc.subject | Nitrogen | en_US |
dc.subject | Polymers | en_US |
dc.subject | Scanning electron microscopy | en_US |
dc.subject | Single crystals | en_US |
dc.subject | Supramolecular chemistry | en_US |
dc.subject | Thermoanalysis | en_US |
dc.subject | X ray diffraction | en_US |
dc.subject | X ray powder diffraction | en_US |
dc.subject | Coordination compounds | en_US |
dc.subject | Natural bond orbital analysis | en_US |
dc.subject | NBO analysis | en_US |
dc.subject | One-dimensional polymers | en_US |
dc.subject | Single crystal x-ray diffraction | en_US |
dc.subject | Ultrasonic assistance | en_US |
dc.subject | Zig-zag | en_US |
dc.subject | Coordination polymers | en_US |
dc.subject | Coordination reactions | en_US |
dc.subject | Nanoparticles | en_US |
dc.title | Preparation of a novel nano-scale lead (II) zigzag metal-organic coordination polymer with ultrasonic assistance: Synthesis, crystal structure, thermal properties and NBO analysis of [Pb(μ-2-pinh)(N3)OH2]n | en_US |
dc.type | Article | en_US |
dc.identifier.wos | 000378841800011 | tr_TR |
dc.identifier.scopus | 2-s2.0-84966708399 | tr_TR |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | tr_TR |
dc.contributor.department | Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. | tr_TR |
dc.contributor.orcid | 0000-0002-2849-3332 | tr_TR |
dc.identifier.startpage | 819 | tr_TR |
dc.identifier.endpage | 828 | tr_TR |
dc.identifier.volume | 26 | tr_TR |
dc.identifier.issue | 4 | tr_TR |
dc.relation.journal | Journal of Inorganic and Organometallic Polymers and Materials | en_US |
dc.contributor.buuauthor | Yılmaz, Veysel Turan | - |
dc.contributor.researcherid | L-7238-2018 | tr_TR |
dc.relation.collaboration | Yurt dışı | tr_TR |
dc.subject.wos | Polymer science | en_US |
dc.indexed.wos | SCIE | en_US |
dc.indexed.scopus | Scopus | en_US |
dc.wos.quartile | Q2 | en_US |
dc.contributor.scopusid | 7006269202 | tr_TR |
dc.subject.scopus | Coordination Polymer; X-Ray Powder Diffraction; Elemental Analyses | en_US |
Appears in Collections: | Scopus Web of Science |
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