1. Açık Erişim@BUU
  2. İndeksli Yayınlar
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Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/32138
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dc.date.accessioned2023-04-03T07:40:44Z-
dc.date.available2023-04-03T07:40:44Z-
dc.date.issued2003-
dc.identifier.citationCoşkun, N. ve Arıkan, N. (2003). “Search for a nonelectrocyclic cyclization of nitrosostyrene: Rearrangements of Michael adducts from DMAD and alpha-dialkylamino oximes”. Turkish Journal of Chemistry, 27(1), 15-20.tr_TR
dc.identifier.issn1010-7614-
dc.identifier.urihttps://journals.tubitak.gov.tr/chem/vol27/iss1/3/-
dc.identifier.urihttp://hdl.handle.net/11452/32138-
dc.description.abstractThe aza-Claisen rearrangement product of the Michael adducts 2 from alpha-dialkylaminoacetophenone oximes and DMAD underwent fragmentation to give dialkylaminomaleate, and benzonitrile at reflux in acetonitrile. The fragmentation was assumed to proceed through an unstable 4H-1,2-oxazete 6. The same reaction performed at room temperature, in addition to the nitrile and maleate, gave the corresponding 2-(2-dialkylamino-1-phenylethylideneaminooxy)-but-2-enedioic acid dimethyl esters 8 and 9. Compounds 9 isomerized to 8 on heating in acetonitrile.en_US
dc.language.isoenen_US
dc.publisherTÜBİTAKtr_TR
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rightsAtıf Gayri Ticari Türetilemez 4.0 Uluslararasıtr_TR
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectChemistryen_US
dc.subjectEngineeringen_US
dc.subjectN-oxidesen_US
dc.titleSearch for a nonelectrocyclic cyclization of nitrosostyrene: Rearrangements of Michael adducts from DMAD and alpha-dialkylamino oximesen_US
dc.typeArticleen_US
dc.identifier.wos000181586900003tr_TR
dc.identifier.scopus2-s2.0-0037219007tr_TR
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.relation.bapNo 2001/2tr_TR
dc.identifier.startpage15tr_TR
dc.identifier.endpage20tr_TR
dc.identifier.volume27tr_TR
dc.identifier.issue1tr_TR
dc.relation.journalTurkish Journal of Chemistryen_US
dc.contributor.buuauthorCoşkun, Necdet-
dc.contributor.buuauthorArıkan, Nevin-
dc.contributor.researcheridAAH-6337-2021tr_TR
dc.contributor.researcheridB-1200-2012tr_TR
dc.indexed.trdizinTrDizintr_TR
dc.subject.wosChemistry, multidisciplinaryen_US
dc.subject.wosEngineering, chemicalen_US
dc.indexed.wosSCIEen_US
dc.indexed.scopusScopusen_US
dc.contributor.scopusid7004177880tr_TR
dc.contributor.scopusid6603961440tr_TR
dc.subject.scopusIsonitrosoacetophenone; Oximes; Acetaldoximeen_US
dc.subject.emtreeAnalytical parametersen_US
dc.subject.emtreeArticleen_US
dc.subject.emtreeChemical proceduresen_US
dc.subject.emtreeCyclizationen_US
dc.subject.emtreeFragmentation reactionen_US
dc.subject.emtreeIsomerismtr_TR
dc.subject.emtreeRoom temperatureen_US
dc.subject.emtreeAcetonitrileen_US
dc.subject.emtreeAmino oximeen_US
dc.subject.emtreeBenzonitrileen_US
dc.subject.emtreeEster derivativeen_US
dc.subject.emtreeMaleic aciden_US
dc.subject.emtreeMaleic acid derivativeen_US
dc.subject.emtreeNitrileen_US
dc.subject.emtreeNitrosostyreneen_US
dc.subject.emtreeOxime derivativeen_US
dc.subject.emtreeStyreneen_US
dc.subject.emtreeUnclassified drugen_US
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