Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene

Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/33491

Title:	Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene
Authors:	Erdem, İhsan Gronert, Scott Cabrera, Gabriel Tapken, Marco Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. Coşkun, Necdet B-1200-2012 7004177880
Keywords:	Chemistry Fulvenes Nucleophilic addition Cycloaddition 1,2-Dihydropentalene Reaction mechanisms Substituted fulvenes Cyclopentadiene Dimethylfulvene Cycloaddition 6,6-dimethylfulvene Elimination Precursors Products Acetone System
Issue Date:	26-May-2017
Publisher:	Wiley-V C H
Citation:	Erden, İ. vd. (2017). ''Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene''. European Journal of Organic Chemistry, 20(2017), 2925-2931.
Abstract:	The title compound exhibits a number of modes of reactivity toward nucleophiles/bases owing to the presence of several electrophilic and potentially nucleophilic sites in the molecule. We explored the reactions of 6-(chloromethyl)-6-methylfulvene with oxygen and nitrogen nucleophiles and bases as well as a carbon-based nucleophile (an enamine) and realized all possible reactivity modes predicted on the basis of electrophilic and nucleophilic positions in this compound.
URI:	https://doi.org/10.1002/ejoc.201700442 https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201700442 http://hdl.handle.net/11452/33491
ISSN:	1434-193X 1099-0690
Appears in Collections:	Scopus Web of Science

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