Selective oxidative deoximation with anhydrous Ce(IV) sulfate

Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/34661

Title:	Selective oxidative deoximation with anhydrous Ce(IV) sulfate
Authors:	Asutay, Oktay Hamarat, Nilüfer Uludağ, Nesimi Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. Coşkun, Necdet B-1200-2012 7004177880
Keywords:	Chemistry Oxidation Oximes Reaction mechanism Hammett correlation Isonitroso hydrogen Parent carbonyl-compounds One-pot synthesis Preparative conversion Efficient Regeneration Derivatives Nitrate
Issue Date:	17-Jun-2015
Publisher:	Elsevier
Citation:	Asutay, O. vd. (2015). "Selective oxidative deoximation with anhydrous Ce(IV) sulfate". Tetrahedron Letters, 56(25), 3902-3904.
Abstract:	Anhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes.
URI:	https://doi.org/10.1016/j.tetlet.2015.04.111 https://www.sciencedirect.com/science/article/pii/S0040403915007686 http://hdl.handle.net/11452/34661
ISSN:	0040-4039
Appears in Collections:	Scopus Web of Science

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