One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones

Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/21779

Title:	One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones
Authors:	Uludağ Üniversitesi/Fen Edebiyat Fakültesi/Kimya Bölümü. Coşkun, Necdet Parlar, Aydın
Keywords:	Acyclic nitrone Oxidation Alkyl hydroxylamine hydrochloride 1,3-Dipolar cycloaddition Oxidation Imidazoline 3-oxides Hydrogen-peroxide Diastereoselective addition Secondary-amines Regio Hydroxylamines Chemistry
Issue Date:	2005
Publisher:	Taylor & Francis
Citation:	Coşkun, N. ve Parlar, A. (2005). "One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones". Synthetic Communications, 35(18), 2445-2451.
Abstract:	Aromatic aldehydes were reductively aminated to the corresponding secondary amines using NaBH4 in methanol in good yields. Amines were oxidized with H2O2-WO42- regioselectively to nitrones, the structures of which were easily determined by reacting them with hydroxylamine hydrochloride as well as by spectral means. The products of hydroxylaminolysis in ether proved to be the corresponding benzaldehyde oximes and benzyl or methyl hydroxylamine hydrochlorides.
URI:	https://doi.org/10.1080/00397910500191169 https://www.tandfonline.com/doi/full/10.1080/00397910500191169 http://hdl.handle.net/11452/21779
ISSN:	0039-7911
Appears in Collections:	Scopus Web of Science

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