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Başlık: Photocatalytic degradation of Congo Red by hydrothermally synthesized nanocrystalline TiO2 and identification of degradation products by LC-MS
Yazarlar: Erdemoğlu, Sema
Sayılkan, Funda
Asiltürk, Meltem
Sayılkan, Hikmet
Frimmel, Fritz
Güçer, Şeref
Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.
0000-0002-1074-3612
Aksu, Songül Karaaslan
İzgi, Belgin
AAE-8564-2020
23984342100
8130734000
Anahtar kelimeler: Congo red
Photocatalytic degradation
TiO2
Degradation product
LC-MS
Advanced oxidation
Azo-dyes
Efficiency
Powder
Water
Dyes
Liquid chromatography
Photocatalysis
Mass spectrometry
Nanocrystalline materials
Photocatalysis
Aqueous solution
Catalysis
Concentration (composition)
Identification method
Irradiation
Oxide
pH
Photodegradation
Titanium
Yayın Tarihi: 15-Tem-2008
Yayıncı: Elsevier
Atıf: Erdemoğlu, S. vd. (2008).''Photocatalytic degradation of Congo Red by hydrothermally synthesized nanocrystalline TiO2 and identification of degradation products by LC-MS''. Journal of Hazardous Materials, 155(3), 469-476.
Özet: Degradation of Congo Red (CR) dye in aqueous solutions was investigated by means of photocatalysis of TiO2 which was hydrothermally synthesized at 200 degrees C in 2 h, in anatase phase with 8 nm crystallite size. Efficiency of TiO2 in photocatalytic degradation under visible irradiation was studied by investigating the effects of amount of TiO2, irradiation time, initial CR concentration and pH. It was found that complete decolorization is achieved within 30 min of irradiation. Effects of nitrate and sulphate ions and humic acid on the degradation were also tested. The results were compared with Degussa P-25 TiO2 at the same degradation conditions. Degradation products were detected using LC-MS technique. The probable pathways for the formation of degradation products were proposed.
URI: https://doi.org/10.1016/j.jhazmat.2007.11.087
https://www.sciencedirect.com/science/article/pii/S0304389407017116
http://hdl.handle.net/11452/22435
ISSN: 0304-3894
1873-3336
Koleksiyonlarda Görünür:Scopus
Web of Science

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