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http://hdl.handle.net/11452/22435
Başlık: | Photocatalytic degradation of Congo Red by hydrothermally synthesized nanocrystalline TiO2 and identification of degradation products by LC-MS |
Yazarlar: | Erdemoğlu, Sema Sayılkan, Funda Asiltürk, Meltem Sayılkan, Hikmet Frimmel, Fritz Güçer, Şeref Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. 0000-0002-1074-3612 Aksu, Songül Karaaslan İzgi, Belgin AAE-8564-2020 23984342100 8130734000 |
Anahtar kelimeler: | Congo red Photocatalytic degradation TiO2 Degradation product LC-MS Advanced oxidation Azo-dyes Efficiency Powder Water Dyes Liquid chromatography Photocatalysis Mass spectrometry Nanocrystalline materials Photocatalysis Aqueous solution Catalysis Concentration (composition) Identification method Irradiation Oxide pH Photodegradation Titanium |
Yayın Tarihi: | 15-Tem-2008 |
Yayıncı: | Elsevier |
Atıf: | Erdemoğlu, S. vd. (2008).''Photocatalytic degradation of Congo Red by hydrothermally synthesized nanocrystalline TiO2 and identification of degradation products by LC-MS''. Journal of Hazardous Materials, 155(3), 469-476. |
Özet: | Degradation of Congo Red (CR) dye in aqueous solutions was investigated by means of photocatalysis of TiO2 which was hydrothermally synthesized at 200 degrees C in 2 h, in anatase phase with 8 nm crystallite size. Efficiency of TiO2 in photocatalytic degradation under visible irradiation was studied by investigating the effects of amount of TiO2, irradiation time, initial CR concentration and pH. It was found that complete decolorization is achieved within 30 min of irradiation. Effects of nitrate and sulphate ions and humic acid on the degradation were also tested. The results were compared with Degussa P-25 TiO2 at the same degradation conditions. Degradation products were detected using LC-MS technique. The probable pathways for the formation of degradation products were proposed. |
URI: | https://doi.org/10.1016/j.jhazmat.2007.11.087 https://www.sciencedirect.com/science/article/pii/S0304389407017116 http://hdl.handle.net/11452/22435 |
ISSN: | 0304-3894 1873-3336 |
Koleksiyonlarda Görünür: | Scopus Web of Science |
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