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http://hdl.handle.net/11452/22988
Başlık: | 2D holodirected lead(II) bromide coordination polymers constructed of rigid and flexible ligands |
Yazarlar: | Aslani, Alireza Morsali, Ali Büyükgüngör, Orhan Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Anabilim Dalı. 0000-0002-2849-3332 Yılmaz, Veysel Turan L-7238-2018 7006269202 |
Anahtar kelimeler: | 1,2-Bis(4-pyridyl)ethane 1,2-Bis(4-pyridyl)ethene 4,4′-Bipyridine Coordination polymer Lead(II) Thermal study Crystal-structure Lone-pair Complexes Compound 2,2'-bipyridine Chemistry Complexation Differential thermal analysis Ethane Ethylene Polymers Single crystals Thermodynamic stability X ray crystallography X rays 1,2-Bis(4-pyridyl)ethene Bipyridines Coordination number Coordination polymers Differential thermal analyses (DTA) Single crystal X-ray data Thermal gravimetric Thermal study Lead compounds |
Yayın Tarihi: | 1-Nis-2009 |
Yayıncı: | Elsevier Science |
Atıf: | Aslani, A. vd. (2009). "2D holodirected lead(II) bromide coordination polymers constructed of rigid and flexible ligands". Inorganica Chimica Acta, 362(5), 1506-1510. |
Özet: | Three new 2D Pb-II coordination polymers containing 4,4'-bipyridine (4,4'-bipy), 1,2-bis(4-pyridyl)ethane (bpa) and 1,2-bis(4-pyridyl) ethene (bpe) with bromide anions, [Pb(mu-4,4'-bipy)(mu-Br)(2)](n) (1), [Pb(mu-bpa)(mu-Br)(2)](n) (2) and [Pb(mu-bpe)(mu-Br)(2)](n) ( 3) have been synthesized and characterized by elemental analysis, IR spectroscopy and their structures studied by X-ray crystallography. The thermal stability of compounds 1-3 was studied by thermal gravimetric (TG) and differential thermal analyses ( DTA). The single-crystal X-ray data shows that the Pb2+-ions have coordination numbers of six and contain the rarely holodirected geometries. |
URI: | https://doi.org/10.1016/j.ica.2008.07.013 https://www.sciencedirect.com/science/article/pii/S0020169308004866 http://hdl.handle.net/11452/22988 |
ISSN: | 0020-1693 |
Koleksiyonlarda Görünür: | Scopus Web of Science |
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