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Başlık: A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure
Yazarlar: Hamamcı, Sevim
Kazak, Canan
Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.
0000-0002-2849-3332
Yılmaz, Veysel Turan
L-7238-2018
7006269202
Anahtar kelimeler: Chemistry
Ag⋯Ag interaction
Ag⋯C interaction
Coordination polymer
Saccharinate
Square-planar silver(I)
Crystal-structure
Thermal-analysis
Complexes
Pyrazine
Ligands
Ftir
ABS resins
Acetonitrile
Flow interactions
Polymers
Silver compounds
Single crystals
Two dimensional
X ray diffraction analysis
Coordination polymer
Coordination polymers
Dimeric molecules
Dinuclear
Elemental analyses
IR spectroscopies
IR spectrum
Layered structures
Planar coordination geometries
Silvers (i)
Single crystal x-ray diffractions
X-ray structures
Coordination reactions
Yayın Tarihi: 15-Ara-2008
Yayıncı: Elsevier
Atıf: Yılmaz, V. T. vd. (2008). ''A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure''. Journal of Organometallic Chemistry, 693(26), 3885-3888.
Özet: A new dinuclear silver(I)-saccharinato (sac) complex with acetonitrile (MeCN), [Ag-2(sac)(2)(MeCN)(2)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by two sac ligands, leading to a short argentophilic contact of 2.9074(3) angstrom. Each silver(I) ion exhibits a square-planar coordination geometry including the Ag-Ag bonds. The individual dimeric molecules are extended into a two-dimensional layered structure by weak Ag center dot center dot center dot Csac(eta(2)) interactions of ca. 3.2 angstrom. These interactions were discussed and compared with those found in the first silver(I)-sac complex [Ag(sac)](n).
URI: https://doi.org/10.1016/j.jorganchem.2008.09.053
https://www.sciencedirect.com/science/article/pii/S0022328X08006165
http://hdl.handle.net/11452/23136
ISSN: 0022-328X
1872-8561
Koleksiyonlarda Görünür:Scopus
Web of Science

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