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http://hdl.handle.net/11452/23136| Title: | A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure |
| Authors: | Hamamcı, Sevim Kazak, Canan Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. 0000-0002-2849-3332 Yılmaz, Veysel Turan L-7238-2018 7006269202 |
| Keywords: | Chemistry Ag⋯Ag interaction Ag⋯C interaction Coordination polymer Saccharinate Square-planar silver(I) Crystal-structure Thermal-analysis Complexes Pyrazine Ligands Ftir ABS resins Acetonitrile Flow interactions Polymers Silver compounds Single crystals Two dimensional X ray diffraction analysis Coordination polymer Coordination polymers Dimeric molecules Dinuclear Elemental analyses IR spectroscopies IR spectrum Layered structures Planar coordination geometries Silvers (i) Single crystal x-ray diffractions X-ray structures Coordination reactions |
| Issue Date: | 15-Dec-2008 |
| Publisher: | Elsevier |
| Citation: | Yılmaz, V. T. vd. (2008). ''A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure''. Journal of Organometallic Chemistry, 693(26), 3885-3888. |
| Abstract: | A new dinuclear silver(I)-saccharinato (sac) complex with acetonitrile (MeCN), [Ag-2(sac)(2)(MeCN)(2)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by two sac ligands, leading to a short argentophilic contact of 2.9074(3) angstrom. Each silver(I) ion exhibits a square-planar coordination geometry including the Ag-Ag bonds. The individual dimeric molecules are extended into a two-dimensional layered structure by weak Ag center dot center dot center dot Csac(eta(2)) interactions of ca. 3.2 angstrom. These interactions were discussed and compared with those found in the first silver(I)-sac complex [Ag(sac)](n). |
| URI: | https://doi.org/10.1016/j.jorganchem.2008.09.053 https://www.sciencedirect.com/science/article/pii/S0022328X08006165 http://hdl.handle.net/11452/23136 |
| ISSN: | 0022-328X 1872-8561 |
| Appears in Collections: | Scopus Web of Science |
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