1. Açık Erişim@BUU
  2. İndeksli Yayınlar
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Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/25361
Title: Solvents effect on infrared spectra of trimethyl phosphate in organic solvents
Authors: Tekin, Nalan
Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.
Cebe, Mustafa
6506210722
Keywords: Chemistry
Spectroscopy
Infrared spectroscopy
Linear solvation energy relationships
Solvent effects
Trimethyl phosphate
Solvation energy relationships
Vibrational frequency-shifts
Pi-star
IR
Systems
NMR
Hydrogen
Equation
Acetone
Solutes
Alkalinity
Hydroxylation
Molecular vibrations
Permittivity
Phosphates
Electronic polarization
Organic compounds
Issue Date: 18-Oct-2004
Publisher: Elsevier
Citation: Tekin, N. ve Cebe, M. (2004). “Solvents effect on infrared spectra of trimethyl phosphate in organic solvents”. Vibrational Spectroscopy, 36(1), 129-133.
Abstract: Infrared spectroscopy studies of trimethyl phosphate (TMP) in 17 different pure organic solvents were undertaken to investigate the solvent-solute interactions and to correlate solvent properties such as the Kirkwood-Bauer-Magat (KBM) equation, the solvent acceptor number (AN) and the linear solvation energy relationships (LSER), respectively, with the infrared band shift. Poor correlation between dielectric constants and the frequencies showed that the KBM relationship was unsuitable for the investigated molecules. These frequencies exhibited a better correlation with the LSER than the solvent AN.
URI: https://doi.org/10.1016/j.vibspec.2004.05.001
http://hdl.handle.net/11452/25361
ISSN: 0924-2031
Appears in Collections:Scopus
Web of Science

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