Please use this identifier to cite or link to this item: http://hdl.handle.net/11452/28706
Title: Synthesis, crystal structure, magnetic, thermal and fluorescent properties of [Co(H2O)4(nia)2](suc)·(H 2suc)
Authors: Demir, Selçuk
Mroziñski, Jerzy
Lis, Tadeusz
Hołyńska, MaŁgorzata
Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.
0000-0002-2849-3332
Yılmaz, Veysel Turan
L-7238-2018
7006269202
Keywords: Succinate complexes
Nicotinamide
Crystal structure
Thermal analysis
Magnetic interaction
Coordination polymers
Aliphatic dicarboxylates
Succinic acid
Architectures
Nicotinamide
Cobalt(II)
Complexes
Ligand
Phen=1,10-phenanthroline
Phenanthroline
Chemistry
Cobalt metallography
Complex networks
Coordination reactions
Crystal structure
Hydrogen bonds
Magnetism
Positive ions
Single crystals
Thermoanalysis
Fluorescent property
Magnetic interactions
Nicotinamide
Octahedral geometry
Single crystal x-ray diffraction
Succinate complexes
Temperature range
Three-dimensional networks
Cobalt compounds
Issue Date: Jun-2010
Publisher: Walter De Gruyter GMBH
Citation: Demir, S. vd. (2010). "Synthesis, crystal structure, magnetic, thermal and fluorescent properties of [Co(H2O)4(nia)2](suc)·(H 2suc)". Zeitschrift fur Naturforschung - Section B-A Journal of Chemical Sciences, 65(6), 695-700.
Abstract: A new cobalt(II) complex, [Co(H2O)(4)(nia)(2)](suc)center dot(H(2)suc) [nicotinamide = nia, succinate = suc(2-)], has been synthesized and characterized by elemental analysis, IR. TG-DTA and single-crystal X-ray diffraction. It contains [Co(H2O)(4)(nia)(2)](2+) complex cations, uncoordinated suc(2-) anios and H(2)suc species. In the complex cation the cobalt(H) ion is coordinated by four aqua and two nia ligands in a distorted octahedral geometry. The suc(2-) dianion acts as a counter-ion, while H(2)suc is present as a molecule of solvation. A three-dimensional network is formed by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. The title complex exhibits luminescence in the solid state at room temperature. The magnetism of the complex was studied over the temperature range 1.8 - 300 K.
URI: https://doi.org/10.1515/znb-2010-0605
https://www.degruyter.com/document/doi/10.1515/znb-2010-0605/html
http://hdl.handle.net/11452/28706
ISSN: 0932-0776
Appears in Collections:Scopus
Web of Science

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.